Repository of problems on Postulates of Quantum Mechanics.All problems fall under "Analysis and Application" levels of Bloom's Taxonomy.
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Obtain solution of the free particle problem in two dimensions using Hamilton Jacobi equation and obtain expression for the Hamilton's principal function.
Problems and Short Questions on Time Development in QM can be found here.
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Consider \(N\) molecules of a gas obeying van der Waals equation of state given by\[\left(P+ \frac{a N^2}{V^2}\right)\big(V-Nb\big) = Nk_B T\]where \(a\) is a measure of the attractive forces between the molecules and \(b\) is another constant proportional to the size of a molecule. The other symbols have their usual meanings. Show that during an isothermal expansion (Temperature is kept onstant) from volume \(V_1\) to volume \(V_2\) quasi-statically and reversibly, the work done is\[ W =-Nk_B T \log\left(\frac{V_2-Nb}{V_1-Nb}\right) + a^2 \Big(\frac{1}{V_1}-\frac{1}{V_2}\Big)\]
This section hs problems on Hamiltonian formulation ofclassical mechanics.
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The molar energy of a monoatomic gas which obeys van der Waal's equation is given by\( E= \frac{3}{2}kT - \frac{a}{v}\),where \(V\) is the volume at temperature \(T\), and \(a\) is a constant. Initially one mole of gas is at temperature \(T_1\) and occupies volume \(V_1\). The gas is allowed to expand adiabatically into a vacuum so that it occpies a total volume \(V_2\). What is the final temperature of the gas?
MANDL
This section has problems on canonical quantization and uncertainty relation.
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