[NOTES/QM-20004] Symmetrization Postulate

Introduction
We now introduce symmetrization postulate for a system of several identical particles. For a system of two identical particles wave function must be chosen to be symmetric or antisymmetric under exchange of space and spin variables, However, at this stage, theoretical considerations alone in non relativistic quantum mechanics, do not help us in deciding which one, symmetric or anti symmetric wave function is the correct choice for a given particle. An appeal to experiment does give an answer which is contained in the statement of the symmetrization postulate. Basically the symmetry property of the total wave function of a system of identical particles is tied to the spin of the particle.

Symmetrization Postulate
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The symmetrization postulate states that

• For a system of {\bf two} identical particles with integral spin bosons the total wave function must be symmetric under simultaneous exchange of all the variables such as the space and spin variables. For a system of two identical particles of half integral spin fermions the full wave function must be anti-symmetric under a simultaneous exchange of all the variables such as the space and spin variables. If $\xi_1,\xi_2$ denote the set of all variables such as, space and spin, of two identical particles. Then the symmetrization postulate states that the total wave function $\psi(\xi_1,\xi_2)$ must be symmetric for bosons and antisymmetric for fermions under an exchange of $\xi_1$ and $\xi_2$. \begin{eqnarray} \psi(\xi_2,\xi_1)&=& + \psi(\xi_1,\xi_2)\qquad\qquad \mbox{( \rm bosons)} \label{E1}\\ \psi(\xi_2,\xi_1)&=& - \psi(\xi_1,\xi_2)\qquad\qquad \mbox{( \rm fermions)} \label{E2} \end{eqnarray}

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• The symmetrization postulate for a system of $n-$ identical particles sates that the total wave function must be symmetric simultaneous under exchange of variables $\xi_j$ and $\xi_k$ for every pair $j,k$, if the particles are bosons and the relation \begin{equation} \psi(\xi_1,\cdot \xi_j\cdots,\xi_k,\cdots,\xi_n)= + \psi(\xi_1,\cdot \xi_k,\cdots,\xi_j,\cdots,\xi_n) \label{E3} \end{equation} should hold for all pairs $AK$. Similarly, for a system of $n-$ identical fermions the total wave function must be anti-symmetric under simultaneous exchange of variables $\xi_j, \xi_k$ for every pair $j,k$ \begin{equation} \psi(\xi_1,\cdot \xi_j\cdots,\xi_k,\cdots,\xi_n) = -\psi(\xi_1,\cdot \xi_k,\cdots,\xi_j,\cdots,\xi_n) \label{E4} \end{equation} For a system of several identical bosons, the total wave function $\Psi(\xi_1,\cdots,\xi_n)$ remains unchanged under an arbitrary permutation of $\xi_1,\cdots,\xi_n$; where as for fermions the wave function remains unchanged under an even permutation but changes sign under an odd permutations.

Remarks

We now give some explanatory remarks on the symmetrization postulate.

1. The postulate is a statement about the {\bf full} wave function of the system of identical particles under a {\bf simultaneous exchange of all} the variables. For example, there is no constraint on the space part (or the spin part) of the wave function alone need.
2. For composite systems such those consisting of both bosons and fermions, the symmetry rrequirementshold for every pair of identical bosons and identical fermions separately.
3. For a system consisting of several 'particles' which themselves could be bound state of bosons and fermions the postulate applies with spin interpreted to mean the total angular momentum at rest.
4. While for a system of two particles the symmetry property is restricted to symmetry or antisymmetry alone, for a system of many identical particles theoretical considerations allow existence of a variety of possibilities under permutation of variables. These choices, known generally as 'para-statistics', do not seem to play any role for real physical systems.