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[QUE/SM-03005] Statistical Mechanics

Consider an isolated system of $N$ non-interacting particles occupying two states of energies $-\epsilon$ and $+\epsilon$. The energy of the system is $E$. Let $x=\displaystyle{\frac{E}{N\epsilon}}.$

  1. Show that the entropy of the system is given by\footnote{HINT : Let $n_1$ and $n_2$ denote the number of particles in the two states of energy $-\epsilon$ and $+\epsilon$ respectively. We have $\widetilde{\Omega}=N!/(n_1!n_2!)$; $S=k_B\ln\widetilde{\Omega}$; Calculate $n_1$ and $n_2$ by solving : $n_1+n_2=N$ and $n_2\epsilon-n_1\epsilon=E$.} $$ S(E)=Nk_B\left[\left(\frac{1+x}{2}\right)\ln\left(\frac{2}{1+x} \right)+\left(\frac{1-x}{2}\right)\ln\left(\frac{2}{1-x}\right)\right] $$
  2. Show that ${\displaystyle \beta=\frac{1}{k_BT}=\frac{1}{2\epsilon}\ln\left(\frac{1-x}{1+x}\right)}$
 
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